Synthesis of Alkyl Halides from Aldehydes via Deformylative Halogenation
نویسندگان
چکیده
منابع مشابه
A mild and efficient procedure for the synthesis of ethers from various alkyl halides
A simple, mild and practical procedure has been developed for the synthesis of symmetrical and unsymmetrical ethers by using DMSO, TBAI in the presence of K2CO3. We extended the utility of Potassium carbonate as an efficient base for the preparation of ethers. A wide range of alkyl aryl and dialkyl ethers are synthesized from treatment of aliphatic alcohols and phenols with various alkyl hali...
متن کاملErratum: Amine synthesis via iron-catalysed reductive coupling of nitroarenes with alkyl halides
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متن کاملAmine synthesis via iron-catalysed reductive coupling of nitroarenes with alkyl halides
(Hetero)Aryl amines, an important class of organic molecules in medicinal chemistry, are most commonly synthesized from anilines, which are in turn synthesized by hydrogenation of nitroarenes. Amine synthesis directly from nitroarenes is attractive due to improved step economy and functional group compatibility. Despite these potential advantages, there is yet no general method for the synthesi...
متن کاملZ-Selective Olefin Synthesis via Iron-Catalyzed Reductive Coupling of Alkyl Halides with Terminal Arylalkynes
Selective catalytic synthesis of Z-olefins has been challenging. Here we describe a method to produce 1,2-disubstituted olefins in high Z selectivity via reductive cross-coupling of alkyl halides with terminal arylalkynes. The method employs inexpensive and nontoxic catalyst (iron(II) bromide) and reductant (zinc). The substrate scope encompasses primary, secondary, and tertiary alkyl halides, ...
متن کاملa mild and efficient procedure for the synthesis of ethers from various alkyl halides
a simple, mild and practical procedure has been developed for the synthesis of symmetrical and unsymmetrical ethers by using dmso, tbai in the presence of k2co3. we extended the utility of potassium carbonate as an efficient base for the preparation of ethers. a wide range of alkyl aryl and dialkyl ethers are synthesized from treatment of aliphatic alcohols and phenols with various alkyl halid...
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ژورنال
عنوان ژورنال: Organic Letters
سال: 2019
ISSN: 1523-7060,1523-7052
DOI: 10.1021/acs.orglett.9b01337